Synthesis and Characterization of Metal Complexes of 2-[5-phenyl(1,3,4-oxadiazole-2-yl) thio]-N`-[(1E)-(4-methyl-(1,3-thiazole-5-yl)methylene)] acetohydrazide
Keywords:
Transition metal complexes, 1,3,4-oxadiazole -2-thiol derivatives, ThiazoleAbstract
The ligand 2-[(5-phenyl-1,3,4-oxadiazole – 2-yl) thio] – N’ – [(1E)- (4-methyl-1,3- thiazole-5-yl)methylene] acetohydrazide was synthesized and the complexes with metal chlorides such as Co(II), Mn(II), Ni(II) and metal perchlorate of Cu(II) were synthesized and characterized on the basis of IR and 1H NMR, UV-Visible, molar conductivity, TGA analysis and magnetic susceptibility measurements. Spectral data reveal that ligands chealated with metal through N-atoms. Magnetic susceptibility measurements favour Octahedral coordination for Cu(II), Ni(II), Mn(II) and Tetrahedral co-ordination for Co(II) metal complexes .